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1.
Urolithiasis ; 52(1): 67, 2024 Apr 17.
Artigo em Inglês | MEDLINE | ID: mdl-38630266

RESUMO

Laser lithotripsy is gaining global prominence and is a dynamically progressing field marked by a continual influx of new and comprehensive research each year. Recently, there has been a noticeable shift toward the adoption of various kinds of lasers, such as holmium: yttrium-aluminum-garnet (Ho:YAG) and thulium fiber (TFL) lasers. Consequently, we aim to conduct a bibliometric analysis to analyze key areas of research activity within scientific publications that center on the utilization of laser techniques in urolithiasis. A search of the literature spanning from 1978 to 2022 was carried out on 25 December 2023 using the Scopus database to explore research related to the application of laser techniques for urolithiasis treatment. Visualization analysis was performed using VOSviewer software (version 1.6.20). We examined 962 publications that met the specified criteria, 791 (82.22%) of which were original articles. The analysis of the retrieved publications indicated a consistent increase in research output from 1978 to 2022; a particularly noteworthy surge occurred after 2003. In particular, the U.S. claimed the leading position as the most productive country, contributing 211 articles (21.93%). However, India had the highest research productivity according to the adjustment index of 19.08. In the European region, 324 publications (33.68% of the total) originated from 25 countries. The Journal of Endourology contributed the most between 1978 and 2022 (n = 96, 9.98%). The most cited paper examined the effectiveness of holmium: yttrium-aluminum-garnet (Ho:YAG) lasers, while a subsequent study focused on the use of a thulium fiber laser (TFL), an emerging laser technology that has gained increased recognition. Co-occurrence analysis revealed three distinct clusters focusing on the types of laser technology, minimally invasive approaches, and success rate/postoperative complications. This comprehensive investigation delves into the global landscape of laser use for the treatment of urolithiasis. This review supports the emerging clinical concept of using various types of laser technology for urolithiasis treatment. Moreover, the hot issues that researchers should focus on based on the findings of this study are the use of different types of laser lithotripsy in view of the surgical approach, success rate and complications.


Assuntos
Alumínio , Hólmio , Túlio , Ítrio , Humanos , Bibliometria , Complicações Pós-Operatórias
2.
Wei Sheng Yan Jiu ; 53(2): 275-281, 2024 Mar.
Artigo em Chinês | MEDLINE | ID: mdl-38604964

RESUMO

OBJECTIVE: To investigate the content of rare earth elements(REs)in blood and hair of residents in a RE mining area in Northwest Hubei, and evaluate the impact of REs on the health status of local residents. METHODS: A total of 191 residents from the core area of RE mining areas and 186 residents from non RE mining areas, aged 20-69, were selected. The content of REs in the blood and hair of the survey subjects was measured using inductively coupled plasma mass spectrometry, and compared with existing literature values. At the same time, blood tests and questionnaire surveys will be conducted on the health status of residents to examine whether human RE enrichment can lead to endemic diseases. RESULTS: The average total content of REs in the blood of residents in the mining area was 60.22 ng/mL, which was 3.35 times that of the control area; The average total content of REs in hair was 1197.91 ng/g, which was 6.32 times higher than the control area. As age increasing, the abundance of REs in the blood and hair of both men and women in mining areas increased. The proportion of Yttrium and Scandium in the blood and hair were much higher than that in the soil. Compared to hair, Yttrium and Scandium were more easily enriched in the blood. There was no significant difference in the probability of fatty liver, hepatitis B, hypoglycemia, hypotension, hypertension and heart disease and the average life span between residents in RE mining areas and those in the control area. CONCLUSION: The high daily average dietary intake of REs in residents leads to a relatively large accumulation of REs in human blood and hair, but no significant and substantial human health damage has been found at present.


Assuntos
Hipertensão , Metais Terras Raras , Masculino , Humanos , Feminino , Escândio/análise , Metais Terras Raras/análise , Cabelo/química , Ítrio/análise , China , Monitoramento Ambiental
3.
Lasers Med Sci ; 39(1): 97, 2024 Apr 01.
Artigo em Inglês | MEDLINE | ID: mdl-38558189

RESUMO

To study the effect range of the Nd:YAG laser through various levels of cloudy medium for targets with varying grayscale values in vitro. The coated paper cards with grayscale values of 0, 50, 100, and 150 were used as the laser's targets, which were struck straightly with varying energies using three burst modes (single pulse, double pulse, and triple pulse). Six filters (transmittances of 40, 50, 60, 70, 80, and 90) were applied to simulate various levels of cloudy refractive medium. Image J software was used to measure the diameters and regions of the laser spots. The ranges of the Nd:YAG laser spots increased with energy in the same burst mode (P < 0.05). Under the same amount of energy, the ranges of the Nd:YAG laser spot increased with the grayscale value of the targets (P < 0.05). The greater the transmittance of the filters employed, the larger the range of the Nd: YAG laser spots produced. Assuming that the total pulse energy is identical, the effect ranges of multi-pulse burst modes were significantly larger than those of single-pulse burst mode (P < 0.05). The effect range of a Nd:YAG laser grows with increasing energy and the target's grayscale value. A cloudy refractive medium has a negative impact on the effect range of the Nd: YAG laser. The single pulse mode has the narrowest and safest efficiency range.


Assuntos
Alumínio , Lasers de Estado Sólido , Lasers de Estado Sólido/uso terapêutico , Conservação de Recursos Energéticos , Ítrio
4.
Luminescence ; 39(4): e4719, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-38637113

RESUMO

The luminescence properties of erbium and yttrium co-doped cadmium difluoride with three different concentrations of yttrium were investigated. First, we synthesized single crystal samples with good optical quality using the Bridgman technique. From the optical absorption spectra, recorded at room temperature, both in the ultraviolet-visible and infrared spectral ranges, Judd-Ofelt analysis was performed based on yttrium concentrations to predict the radiative properties of Er3+ luminescent ions. For the 10% optimum concentration of yttrium, a detailed photoluminescence investigation was carried out. We mainly explored green, red, and near-infrared fluorescence under different excitation wavelengths and presented their highlight spectroscopic characteristics. The desired transitions had relatively high emission cross-sections both under visible and near-infrared excitation. Optical gain followed a similar trend. Furthermore, the dynamic fluorescence study showed a significant increase in the measured lifetime under an 800 nm infrared excitation. The upconversion process under an 800 nm excitation produced quantum efficiency greater than 100% due to the contribution of more than one energy transfer mechanism.


Assuntos
Érbio , Luminescência , Íons , Fluorescência , Érbio/química , Ítrio/química
5.
Zhonghua Yan Ke Za Zhi ; 60(4): 370-373, 2024 Apr 11.
Artigo em Chinês | MEDLINE | ID: mdl-38583061

RESUMO

A 62-year-old female patient presented with no improvement in vision 10 days after undergoing cataract extraction in the right eye. The unaided visual acuity in the right eye was 0.1, and examination with a slit lamp revealed the presence of the intraocular lens with an increased gap between the intraocular lens and the posterior capsule. Anterior segment optical coherence tomography showed a distance of 3.236 mm between the posterior capsule and the posterior surface of the intraocular lens. Based on the medical history, ocular examination, and auxiliary examinations, a diagnosis of right eye capsular blockage syndrome was made. Nd:YAG laser capsulotomy was performed at the anterior capsule outside the optical zone of the intraocular lens. One week later, the posterior capsule adhered to the posterior surface of the intraocular lens, and there was a significant improvement in vision compared to before the procedure.


Assuntos
Terapia a Laser , Lasers de Estado Sólido , Cápsula do Cristalino , Feminino , Humanos , Pessoa de Meia-Idade , Cápsula do Cristalino/cirurgia , Neodímio , Alumínio , Lasers de Estado Sólido/uso terapêutico , Terapia a Laser/métodos , Ítrio , Complicações Pós-Operatórias
8.
BMC Oral Health ; 24(1): 309, 2024 Mar 05.
Artigo em Inglês | MEDLINE | ID: mdl-38443872

RESUMO

BACKGROUND: Recent forms of translucent zirconia material have been developed, offering a wide range of options and varieties for enhancing aesthetics, making it a preferred choice in the field of prosthetic dentistry. However, there is insufficient understanding regarding the recent types of zirconia materials and their optical behavior. Understanding the variables that influence the translucency of zirconia and identifying strategies to enhance its esthetics are crucial. PURPOSE: The current systemic review highlights a comprehensive understanding of different zirconia generations in relation to their optical characteristics and evaluates material-related variables affecting their translucency. METHODS: The present review studied in-vitro studies that evaluated the optical characteristics of different yttria content of yttria stabilized materials. The topics explored were: (1) the different zirconia material generations and their optical behavior; (2) material-related factors that affect their translucency. The research was restricted to online publication in the English language from July 1, 2010, to July 31, 2023, using PubMed, Scopus, and Science Direct resources. The search key terms and their combinations were "zirconia," "translucent zirconia," "cubic zirconia," "highly translucent zirconia," "yttria partially stabilized zirconia," "monolithic zirconia," "translucency," "optical properties," and "light transmission." RESULTS: The data obtained from fifty-three studies addressed the optical characteristics of various zirconia generations. They reported that changing yttria content had a significant impact on translucency. Different kinds of zirconia ceramics of the same generation have varying translucencies. Achieving optimum aesthetics with monolithic zirconia is challenging due to factors related to material aspects such as the presence of additives, point defects, microstructure, thickness, phase distribution, and sintering conditions. CONCLUSIONS: Newly developed monolithic dental zirconia ceramics have improved aesthetics and translucency. However, additional research is necessary to evaluate their performance and long-term durability. TRIAL REGISTRATION: This systematic review was registered in PROSPERO, under number CRD42023474482.


Assuntos
Cerâmica , Idioma , Ítrio , Zircônio , Prostodontia
9.
Phys Med Biol ; 69(7)2024 Mar 26.
Artigo em Inglês | MEDLINE | ID: mdl-38529716

RESUMO

Objective. Lutetium yttrium oxyorthosilicate (LYSO) scintillation crystals are used in positron emission tomography (PET) due to their high gamma attenuation, fair energy resolution, and fast scintillation decay time. The enduring presence of the176Lu isotope, characterized by a half-life of 37.9 billion years, imparts a consistent radiation background (BG) profile that depends on the geometry and composition attributes of the LYSO crystals.Approach. In this work, we proposed a methodology for estimating the composition of LYSO crystals in cases where the exact Lutetium composition remains unknown. The connection between BG spectrum intensity and intrinsic radioactivity enables precise estimation of Lutetium density in LYSO crystal samples. This methodology was initially applied to a well-characterized LYSO crystal sample, yielding results closely aligned with the known composition. The composition estimation approach was extended to several samples of undisclosed LYSO crystals, encompassing single crystal and crystal array configurations. Furthermore, we model the background spectrum observed in the LYSO-based detector and validate the observed spectra via simulations.Main results. The estimated Lutetium composition exhibited adequate consistency across different samples of the same LYSO material, with variations of less than 1%. The result of the proposed approach coupled with the simulation successfully models the background radiation spectra in various LYSO-based detector geometries.Significance. The implications of this work extend to the predictive assessment of system behaviors and the autonomous configuration parameters governing LYSO-based detectors.


Assuntos
Lutécio , Ítrio , Lutécio/química , Tomografia por Emissão de Pósitrons/métodos , Silicatos/química
10.
Arq Bras Oftalmol ; 87(3): e20220058, 2024.
Artigo em Inglês | MEDLINE | ID: mdl-38537037

RESUMO

Capsulotomy with neodymium-doped yttriumaluminum-garnet (Nd:YAG) laser is an effective treatment for posterior capsule opacification following cataract surgery. A wide opening of the posterior capsule associated with the ruptured anterior hyaloid can cause anterior chamber vitreous prolapse. Two patients who developed angle-closure glaucoma associated with vitreous prolapse following Nd:YAG laser posterior capsulotomy were successfully treated with antiglaucoma medication and peripheral iridotomies. Patient identification for potential risk factors and a careful postoperative follow-up are essential to avoid these serious complications.


Assuntos
Opacificação da Cápsula , Extração de Catarata , Glaucoma de Ângulo Fechado , Terapia a Laser , Lasers de Estado Sólido , Cápsula do Cristalino , Humanos , Cápsula do Cristalino/cirurgia , Neodímio , Glaucoma de Ângulo Fechado/etiologia , Glaucoma de Ângulo Fechado/cirurgia , Capsulotomia Posterior , Ítrio , Extração de Catarata/efeitos adversos , Prolapso , Terapia a Laser/efeitos adversos , Complicações Pós-Operatórias/etiologia , Lasers de Estado Sólido/efeitos adversos
11.
Int J Mol Sci ; 25(4)2024 Feb 13.
Artigo em Inglês | MEDLINE | ID: mdl-38396933

RESUMO

Bioinert materials such as the zirconium dioxide and aluminum oxide are widely used in surgery and dentistry due to the absence of cytotoxicity of the materials in relation to the surrounding cells of the body. However, little attention has been paid to the study of metabolic processes occurring at the implant-cell interface. The metabolic activity of mouse 3T3 fibroblasts incubated on yttrium-stabilized zirconium ceramics cured with aluminum oxide (ATZ) and stabilized zirconium ceramics (Y-TZP) was analyzed based on the ratio of the free/bound forms of cofactors NAD(P)H and FAD obtained using two-photon microscopy. The results show that fibroblasts incubated on ceramics demonstrate a shift towards the free form of NAD(P)H, which is observed during the glycolysis process, which, according to our assumptions, is related to the porosity of the surface of ceramic structures. Consequently, despite the high viability and good proliferation of fibroblasts assessed using an MTT test and a scanning electron microscope, the cells are in a state of hypoxia during incubation on ceramic structures. The FLIM results obtained in this work can be used as additional information for scientists who are interested in manufacturing osteoimplants.


Assuntos
Interface Osso-Implante , NAD , Zircônio , Animais , Camundongos , Óxido de Alumínio , Cerâmica/química , Fibroblastos/metabolismo , Teste de Materiais , NAD/metabolismo , Propriedades de Superfície , Ítrio , Zircônio/química
12.
Dent Mater J ; 43(2): 263-268, 2024 Mar 29.
Artigo em Inglês | MEDLINE | ID: mdl-38382941

RESUMO

In this study, we investigated the effects of surface treatment on the fracture strength of porcelain-veneered zirconia. Highly translucent 4 mol% yttria-stabilized zirconia disks (KATANA HT, Kuraray Noritake Dental) were divided into three surface-treatment groups: 1)as-sintered, 2) alumina sandblasted, and 3) ground. Crystallographic and surface-roughness analyses were conducted for each group. Veneering ceramics (Cerabien ZR, Kuraray Noritake Dental) were applied to the zirconia surfaces. The fracture strengths of the porcelain-veneered zirconia disks were measured using biaxial flexural-strength tests. Crystallographic analysis revealed that grinding and sandblasting increased the fractions of the monoclinic and rhombohedral zirconia phases. The ground specimens had a higher surface roughness than the sandblasted specimens. Weibull analysis showed no significant differences in biaxial flexural strength among the three groups. The results suggest that these surface treatments do not affect the fracture strength of porcelain-veneered zirconia.


Assuntos
Porcelana Dentária , Resistência à Flexão , Porcelana Dentária/química , Teste de Materiais , Facetas Dentárias , Propriedades de Superfície , Análise do Estresse Dentário , Materiais Dentários/química , Cerâmica/química , Zircônio/química , Ítrio/química
13.
Dent Mater J ; 43(2): 216-226, 2024 Mar 29.
Artigo em Inglês | MEDLINE | ID: mdl-38417860

RESUMO

This study aimed to investigate the effects of sandblasting on the physical properties and bond strength of two types of translucent zirconia: niobium-oxide-containing yttria-stabilized tetragonal zirconia polycrystals ((Y, Nb)-TZP) and 5 mol% yttria-partially stabilized zirconia (5Y-PSZ). Fully sintered disc specimens were either sandblasted with 125 µm alumina particles or left as-sintered. Surface roughness, crystal phase compositions, and surface morphology were explored. Biaxial flexural strength (n=10) and shear bond strength (SBS) (n=12) were evaluated, including thermocycling conditions. Results indicated a decrease in flexural strength of 5Y-PSZ from 601 to 303 MPa upon sandblasting, while (Y, Nb)-TZP improved from 458 to 544 MPa. Both materials significantly increased SBS after sandblasting (p<0.001). After thermocycling, (Y, Nb)-TZP maintained superior SBS (14.3 MPa) compared to 5Y-PSZ (11.3 MPa) (p<0.001). The study concludes that (Y, Nb)-TZP is preferable for sandblasting applications, particularly for achieving durable bonding without compromising flexural strength.


Assuntos
Materiais Dentários , Nióbio , Óxidos , Materiais Dentários/química , Teste de Materiais , Propriedades de Superfície , Zircônio/química , Ítrio/química , Óxido de Alumínio , Resistência ao Cisalhamento
14.
Dent Mater ; 40(4): 664-673, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-38378371

RESUMO

OBJECTIVES: To investigate the impacts of speed and high-speed sintering on the densification, microstructure, phase composition, translucency, and flexural strength of yttria-stabilized zirconia (YSZ). METHODS: A total of 162 disc-shaped specimens (n = 18) were cold-isostatically pressed from 3YSZ (Zpex), 4YSZ (Zpex 4), and 5YSZ (Zpex Smile) powders (Tosoh Corporation) and sintered according to the following protocols: conventional (control, ∼12 h), speed (∼28 min for 3YSZ; ∼60 min for 4YSZ and 5YSZ), and high-speed (∼18 min) sintering. Dimensions of zirconia specimens after sintering and polishing (1-µm diamond grit finish) were Ø13.75 × 1 mm. Density, microstructure, phase content, translucency parameter, and biaxial flexural strength were evaluated using Archimedes', SEM, XRD, spectrophotometric, and piston-on-3-ball methods, respectively. Data were analyzed with either one-way ANOVA and Tukey's test or Kruskal-Wallis with Dunn's test (α = 0.05). RESULTS: For all YSZ compositions, conventional sintering yielded the highest density followed by speed then high-speed sintering. All sintering protocols resulted in similar strength values; however, speed and high-speed sintering protocols afforded significantly lower translucency relative to conventional sintering. XRD analysis revealed similar spectra for YSZs sintered by various protocols. The speed sintered specimens had the smallest grain size whereas the high-speed sintered 5YSZ possessed the largest grain size among all groups. SEM examination of all YSZ compositions revealed that the average pore size was an order of magnitude smaller than the average grain size. SIGNIFICANCE: Speed and high-speed sintering of YSZs yield similar strength but diminished density and translucency relative to their conventionally sintered counterparts.


Assuntos
Cerâmica , Materiais Dentários , Materiais Dentários/química , Cerâmica/química , Teste de Materiais , Propriedades de Superfície , Zircônio/química , Ítrio/química
15.
Dent Mater ; 40(4): 653-663, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-38378372

RESUMO

OBJECTIVE: This study aimed to compare the four-point flexural strength of CAM-milled and sintered (as-sintered, AS) specimens with those of high-polished (HP) specimens using chairside polishing systems to simulate clinical surface conditions. METHODS: Seven full-contour zirconia CAM/CAM blanks with various yttria contents (3, 4, 5 mol%) including three high-translucent groups (5Y) were selected to prepare flexural specimens. The bend bar specimens (2.0 × 4.0 × 25.0 mm3) were fabricated by using STL file and dental CAM machine with the respective zirconia blanks (98 mm ϕ and 10-14 mm in height). Twelve bar specimens were machined from one zirconia puck and a total of 24 specimens were prepared from each group. The pre-sintered bar specimens were sintered by using a dental zirconia furnace at 1530-1550 °C for 2 h according to the instructions. All sintered specimens were divided into two groups: as-sintered (AS) group and high-polished (HP) groups (n = 12). HP groups were subjected to polishing one surface of specimens using a three-step polishing system and finally finished with diamond polishing. After cleaning and drying, the flexural strength of all specimens was determined by a fully articulating four-point flexure fixture consisting of a 1/4-point test configuration with an inner/outer span of 10/20 mm. Statistical differences between AS and HP groups were conducted with Weibull analysis. The fractured surfaces of zirconia specimens were observed using a field emission SEM and EDS to detect failure origins. RESULTS: The mean AS flexural strength values were significantly lower than those of HP counterparts. However, Weibull moduli expressing the reliability of HP groups were generally decreased although not significantly in comparison to their AS. The fracture of the AS specimens mostly originated from extrinsic CAM-milling defects, while the HP specimens were fractured from intrinsic subsurface or volume defects including pores, large grain clusters, inclusions, and corner-located critical flaws. Two high-translucent (5Y) zirconia groups were not affected in their strength and reliability after polishing, whereas one 5Y zirconia significantly increased its strength but significantly lowered its reliability. SIGNIFICANCE: The extrinsic and intrinsic strength-limiting defects should be considered in evaluating the flexural strength and reliability of dental CAD/CAM zirconia ceramics for full-contour restorations. For the materials tested in this study, more optimized processing of blanks and milling protocols of pre-sintered zirconia blanks should be developed including post-sintering surface finishing to reduce the flaw population regulating strength and reliability which will affect the survivability of dental zirconia prostheses.


Assuntos
Cerâmica , Materiais Dentários , Teste de Materiais , Reprodutibilidade dos Testes , Zircônio , Propriedades de Superfície , Ítrio
16.
Dent Mater ; 40(4): 747-755, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-38418282

RESUMO

OBJECTIVE: The objective of this study was to 1) compare the stress corrosion coefficient (n) of a Y-TZP obtained by two fatigue tests: cyclic and dynamic and 2) evaluate the effect of frequency in the characteristic lifetime and the existence of interaction between the cyclic fatigue and slow crack growth. METHODS: A total of 145 Y-TZP specimens were produced in accordance with the manufacturer's instructions. These specimens, measuring 4.0 × 3.0 × 25.0 mm, were used for dynamic (n = 70) and cyclic fatigue tests (n = 75). The specimens were obtained from CAD/CAM blocks, sectioned, and sintered in a furnace at 1530 °C with a heating rate of 25 °C/min. They were tested in their "as-sintered" form without any additional surface treatment. The fatigue tests were conducted using a four-point bending to obtain the slow crack growth parameters (n). The cyclic fatigue test was also conducted in two frequencies (2 and 10 Hz), using stress levels between 350 and 600 MPa. Data from these tests were analyzed using ASTM C 1368-00 formulas and Weibull statistics. Scanning electron microscope (SEM) was used for fracture surface analysis to identify the origin of the fracture. Critical defect size was measured and used, along with flexural strength values, to estimate fracture toughness. Dynamic fatigue test data were used to obtain subcritical crack growth (SCG) parameters and perform Weibull statistical analysis. The cyclic fatigue data were used in the General Log-linear Model equation using the ALTA PRO software. Data were analyzed using one-way ANOVA followed by Tukey post-hoc tests and Student's t-test at a significance level of p ≤ 0.05. RESULTS: In the dynamic fatigue test, the values obtained for σfo and n were 667 and 54, respectively. This parameter indicates how the strength of the material diminishes over time due to internal cracks. The Weibull parameters obtained from the same test results were m = 7.9, σ0 = 968, 9 and σ5% = 767, which indicates the reliability of the material. The Weibull parameters obtained by cyclic fatigue were statistically similar for the two frequencies used, the m* was 0.17 (2 Hz) and 0.21 (10 Hz); characteristic lifetimes (η) were 1.93 × 106 and 40,768, respectively. The n values obtained by cyclic fatigue were 48 and 40 at frequencies of 2 and 10 Hz, respectively. There was no effect of the frequency, the stress level or the interaction of the two in the Y-TZP lifetime, when analysed by General Log Linear Model. SIGNIFICANCE: the n values obtained by cyclic and dynamic fatigue tests showed no statistically significant difference and the effect of frequency in the characteristic lifetime and the existence of interaction between the cyclic fatigue and subcritical growth were not observed in the tested specimens.


Assuntos
Porcelana Dentária , Resistência à Flexão , Reprodutibilidade dos Testes , Teste de Materiais , Análise do Estresse Dentário , Zircônio , Propriedades de Superfície , Cerâmica , Ítrio
17.
Environ Pollut ; 345: 123499, 2024 Mar 15.
Artigo em Inglês | MEDLINE | ID: mdl-38350535

RESUMO

Rare earth elements (REEs) are widely utilized in industries. However, The specific exposure features of REEs and potential biomarkers of exposure in occupational populations remain unclear. In this study, we evaluated the external and internal REEs exposure levels among the participants working in the ionic rare earth smelting plant. For the external exposure, the concentrations of 14 REEs and total rare earth elements (ΣREEs) in airborne particles were significantly elevated in the REEs-exposed versus non-exposed group (P < 0.05). Meanwhile, the levels of Yttrium (Y), Gadolinium (Gd), Terbium (Tb), Dysprosium (Dy), Holmium (Ho), Thulium (Tm), Ytterbium (Yb), and ΣREEs in urine were higher in the REEs-exposed group compared to the non-exposed group (P < 0.05). Notably, a significant positive correlation was observed between Y in both the airborne particles and urine samples as well as Gd, and the Spearman correlation coefficient was 0.53 and 0.39 respectively, both P < 0.05. Conversely, no statistically significant differences were found in the levels of 15 REEs or ΣREEs in the blood samples between the REEs-exposed group and non-exposed group. Moreover, the concentrations of ΣREEs and 9 REEs in nail samples of the exposed group were significantly higher than those of the non-exposed group (P < 0.05), and the composition ratios of REEs in the nail samples closely resembled those found in individual airborne particles. Therefore, nail and urine samples were proposed to reflect long-term and short-term exposure to ionic rare earth respectively. Exposure biomarkers confirmed by external and internal exposure characteristics accurately provide the situation of human exposure to REEs environment, and have profound significance for monitoring and evaluating the level of REEs pollution in human body. It also provides a vital basis to find out the effect biomarkers, susceptible biomarkers and the health effects of rare earth environment for the future research.


Assuntos
Metais Terras Raras , Humanos , Ítrio , Disprósio , Biomarcadores
18.
J Biomed Mater Res B Appl Biomater ; 112(2): e35390, 2024 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-38356151

RESUMO

Silane chemistry has emerged as a powerful tool for surface modification, offering a versatile means to enhance the properties of various substrates, such as dental implant abutment materials. In this study, we investigated the stability of the 3-aminopropyldiisopropylethoxysilane (APDS) layer on yttria-partially stabilized zirconia (Y-TZP) surfaces after mechanical, acid, and thermal treatment in order to simulate fluctuations within the oral cavity. To accomplish that, the viability of human gingival fibroblasts on APDS-modified surfaces after applied treatment strategies was assessed by live/dead staining. Moreover, the hydrolysis stability and enzymatic degradation resistance of crosslinked fibronectin to the APDS layer was examined by immunostaining and western blot. The results revealed that the applied modifications were not affected by the different treatment conditions and could withstand the fluctuations in the oral cavity. Furthermore, crosslinked fibronectin on silanized Y-TZP was stable against hydrolysis over 21 days and enzymatic degradation. We thus can conclude that the proposed functionalization method has high potential to tolerate harmful effects within the oral cavity and remains unchanged on the surface.


Assuntos
Fibronectinas , Zircônio , Humanos , Microscopia Eletrônica de Varredura , Teste de Materiais , Propriedades de Superfície , Zircônio/química , Ítrio/química , Materiais Dentários
19.
World J Urol ; 42(1): 79, 2024 Feb 14.
Artigo em Inglês | MEDLINE | ID: mdl-38353743

RESUMO

PURPOSE: To identify laser settings and limits applied by experts during laser vaporization (vapBT) and laser en-bloc resection of bladder tumors (ERBT) and to identify preventive measures to reduce complications. METHODS: After a focused literature search to identify relevant questions, we conducted a survey (57 questions) which was sent to laser experts. The expert selection was based on clinical experience and scientific contribution. Participants were asked for used laser types, typical laser settings during specific scenarios, and preventive measures applied during surgery. Settings for a maximum of 2 different lasers for each scenario were possible. Responses and settings were compared among the reported laser types. RESULTS: Twenty-three of 29 (79.3%) invited experts completed the survey. Thulium fiber laser (TFL) is the most common laser (57%), followed by Holmium:Yttrium-Aluminium-Garnet (Ho:YAG) (48%), continuous wave (cw) Thulium:Yttrium-Aluminium-Garnet (Tm:YAG) (26%), and pulsed Tm:YAG (13%). Experts prefer ERBT (91.3%) to vapBT (8.7%); however, relevant limitations such as tumor size, number, and anatomical tumor location exist. Laser settings were generally comparable; however, we could find significant differences between the laser sources for lateral wall ERBT (p = 0.028) and standard ERBT (p = 0.033), with cwTm:YAG and pulsed Tm:YAG being operated in higher power modes when compared to TFL and Ho:YAG. Experts prefer long pulse modes for Ho:YAG and short pulse modes for TFL lasers. CONCLUSION: TFL seems to have replaced Ho:YAG and Tm:YAG. Most laser settings do not differ significantly among laser sources. For experts, continuous flow irrigation is the most commonly applied measure to reduce complications.


Assuntos
Alumínio , Túlio , Neoplasias da Bexiga Urinária , Ítrio , Humanos , Túlio/uso terapêutico , Neoplasias da Bexiga Urinária/cirurgia , Lasers , Tecnologia
20.
Int J Prosthodont ; 37(1): 72-79, 2024 Feb 21.
Artigo em Inglês | MEDLINE | ID: mdl-38381986

RESUMO

PURPOSE: To investigate the biaxial flexural strength of zirconia materials with different translucency before and after aging procedures and to evaluate the effects of aging on hardness and surface characteristics. MATERIALS AND METHODS: A total of 90 disc-shaped specimens (n = 30 each) were prepared from translucent (Upcera-ST, Upcera Dental), high translucent (Katana HT, Kuraray Noritake), and ultra high translucent (Katana UTML, Kuraray Noritake) zirconia materials to a ø.16 ±1.2 mm thickness. The different translucency discs were then divided into three subgroups; one group was subjected to aging in a chewing simulator (n = 10), one group was aged with thermocycling (n = 10), and one was a control group (n = 10). Biaxial flexural strength, Vickers hardness, and surface characteristics were examined for all discs. The data were analyzed using the Shapiro-Wilk (P = .05), Mann-Whitney U, and Kruskal-Wallis H tests. Fracture strength was determined using biaxial bending strength tests, and Weibull analysis was used to analyze the resulting data. RESULTS: A statistically significant difference was found among zirconia materials with different translucency in terms of fracture strength. On average, fracture strength was highest in the Upcera ST group (1,932.87 MPa) and lowest in the Katana UTML group (1,073.6 MPa; P = .001). The results of Weibull analysis showed a statistically similar distribution for all groups. CONCLUSIONS: Aging procedures did not cause significant differences in fracture strength and hardness. The fracture strength of the zirconia materials with different translucency was considered acceptable for intraoral use.


Assuntos
Materiais Dentários , Resistência à Flexão , Teste de Materiais , Zircônio , Propriedades de Superfície , Cerâmica , Ítrio
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